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The launch of the satellites of the Sentinel-2 mission has opened a new era of possibilities in precision agriculture. The objective of the present work was to explore the use of Sentinel-2 visible, red-edge and near infrared bands to predict barley (Hordeum vulgare L.) yield in early spring phenological stages at field level. Spectral vegetation indices for different dates were analysed together with apparent electrical conductivity (ECa) to obtain the best linear model to predict yield in critical moments of the barley cycle, in which it is still possible to apply variable rates of sidedress fertilizer to improve yield. The research was carried out in 2017 in a farm located in NE Spain. ECa surveys were by means of a Veris 3100 ECa surveyor and yield data were acquired by means of a yield monitor. Images acquired the first week of April (barley Zadoks DC 30-32) were the ones presenting the best correlation with yield. Multiple regression models resulted in R2 values of 0.75, confirming that vegetation indices from the first week of April produced lower prediction error than earlier dates.